The Pokemon can be obtained from a man at any Pokemon Center in the game.
If you wish to get a specific Nature or Individual Values, save before talking to the delivery man.
No other Piplup can learn the moves Sing and Round.
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Each Piplup will have a Classic Ribbon attached to it. Genesect is an extremely rare Pokemon introduced in this generation.
Make sure to get your hands on it as soon as possible!
Take Meoetta to Cafe Sonata in Castelia City to teach it this move.
This special Piplup will know two very rare moves for its species.
For Wi-Fi Events, select "Receive Gift" from the Mystery Gift Menu at the Main Menu, then choose Wi-Fi to receive your Event Pokemon.
For Location Events, select "Receive Gift" from the Mystery Gift Menu at the Main Menu, then choose Wireless to receive your Event Pokemon.
It's one of many Pokemon that can change its Form in battle.